As for the dangers of silicone, has it occurred to anyone that parchment is not just paper? It has been either treated or coated. Info from Wikipedia:
Parchment paper
Modern parchment paper is made by running sheets of paper pulp through a bath of sulfuric acid (a method similar to how tracing paper is made) or sometimes zinc chloride. This process partially dissolves or gelatinizes the paper. This treatment forms a sulfurized cross-linked material with high density, stability, and heat resistance, and low surface energy – thereby imparting good non-stick or release properties. The treated paper has an appearance similar to that of traditional parchment.
Bakery release paper
The stickless properties can be also achieved by employing a coated paper, for which a suitable release agent — a coating with a low surface energy and capability to withstand the temperatures involved in the baking or roasting process — is deposited onto the paper's surface; silicone (cured with a suitable catalyst) is frequently used.