Trippgal

ummmm. No. The starches in a mash are what works with added enzymes and yeast to make the mixture which then ferments and breaks the starches and sugars down into alcohol. the mash has the potatoes and thus potato starch, but the alcohol that comes from any mash (potato, corn, barley, fruit, etc) comes from heating the mixture to a point where the alcohol begins to evaporate before the boiling point of the water. It is then condensed as the vapor travels through a series of coiled tubes, or chilled condenser assembly and collected into the collection tank.

And please do not ask how I know. Just let's leave it that I have a creative family on my papa's side.....

Vodka is essentially water and alcohol, with hints of the volatile flavors compounds that come from the mash components. Everclear is cleaner tasting and more volatile (more alcohol less water) and i use for a variety of crafting uses.