You can try Grandma's Spot Remover or syntrapol on the stains. I wouldn't wash the quilt yet - you'll have a real mess on your hands then. There's a chance that when you are done and was the quilt with color catchers, all the stains will disappear.
I would also try using distilled water or bottled water to spritz the quilt - or try it on a scrap of the red and see what happens. Different water sources will react differently to the fabric.
Janet