Is the bedskirt cotton or poly/cotton? Will it need ironing after washing? I used to have a bed and breakfast. Some of the skirts needed a lot of ironing as they were 100% cotton and lacy. What a pain! If you merely attach the skirt to the quilt you may find the same thing is needed. Yet do you want to attach cotton/poly to a 100% cotton quilt? It will work but I think having a neutral bedspread underneath the quilt would be wiser in the long run.