different brands of 100% polyester behave differently - especially when it comes to irons.
i have used some that went all flat and stiff under the iron and stayed that way.
some have flattened but fluffed up nicely after the first wash.
if you have already purchased the batting it's likely to be a big enough piece that you can do a potholder-sized test.
if you have not already purchased it, consider going 80/20.
if it's going to be on a dining table, seriously consider insulbrite (or other brand of the same type product.)
then you can safely set hot serving dishes on it.
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