From the Customer Support section of eBay. Looks like you have less control when you use the cart.
http://pages.ebay.com/help/pay/paypal.html
To pay for multiple items using eBay checkout:- Go to My eBay.
- Click Purchase history on the left side of the page.
- Click the Pay for All PayPal Items button on the bottom of the page. This option is only available if you purchased items from multiple sellers who offer PayPal as a payment method.
- Make sure that your shipping address is correct. The seller may require a credit card billing address registered with PayPal, sometimes called a confirmed address.
- Check the order details, including shipping and taxes.
- Click Continue. If you have questions about the total cost, click Request total from seller.
- Select PayPal as your payment method, and log in to your PayPal account.
- Click Continue.
- To complete your purchase, click Confirm Your Payment.